AP Chemistry
9.9 Cell Potential and Free Energy
9.8 Galvanic (Voltaic) and Electrolytic Cells
A student investigates whether copper metal can provide the electrons needed to recover nickel metal from a solution. The proposed reaction is
\(\text{Ni}^{2+}\text{(aq)}+\text{Cu(s)}\rightarrow\text{Ni(s)}+\text{Cu}^{2+}\text{(aq)}\)
The relevant standard reduction potentials are shown below.
The experiment is conducted at \(25^\circ\text{C}\) with both aqueous ions initially at \(1.0\text{ M}\). Which choice correctly indicates whether the proposed reaction is thermodynamically favorable under standard conditions and whether an external voltage source is required to sustain the reaction as written?
\(\text{Ni}^{2+}\text{(aq)}+\text{Cu(s)}\rightarrow\text{Ni(s)}+\text{Cu}^{2+}\text{(aq)}\)
The relevant standard reduction potentials are shown below.
| Reduction half-reaction | \(E^\circ\) |
|---|---|
| \(\text{Ni}^{2+}\text{(aq)}+2e^-\rightarrow\text{Ni(s)}\) | \(-0.25\text{ V}\) |
| \(\text{Cu}^{2+}\text{(aq)}+2e^-\rightarrow\text{Cu(s)}\) | \(+0.34\text{ V}\) |
The experiment is conducted at \(25^\circ\text{C}\) with both aqueous ions initially at \(1.0\text{ M}\). Which choice correctly indicates whether the proposed reaction is thermodynamically favorable under standard conditions and whether an external voltage source is required to sustain the reaction as written?
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