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AP Chemistry
6.7 Bond Enthalpies
6.1 Endothermic and Exothermic Processes
IntermediateMCQMathematicalConceptual17.4k
A student investigates the thermochemistry of the stepwise hydrogenation of ethyne, represented by the two balanced chemical equations below.

\[ \text{Reaction 1: } \text{C}_2\text{H}_2\text{(g)} + \text{H}_2\text{(g)} \rightarrow \text{C}_2\text{H}_4\text{(g)} \]
\[ \text{Reaction 2: } \text{C}_2\text{H}_4\text{(g)} + \text{H}_2\text{(g)} \rightarrow \text{C}_2\text{H}_6\text{(g)} \]

The student references the following table of average bond enthalpies:

BondAverage bond enthalpy (\(\text{kJ/mol}\))
\(\text{C}-\text{C}\)\(350\)
\(\text{C}=\text{C}\)\(610\)
\(\text{C}\equiv\text{C}\)\(840\)
\(\text{C}-\text{H}\)\(410\)
\(\text{H}-\text{H}\)\(435\)

Based on the data in the table, which of the following correctly compares the standard enthalpy change of Reaction 1 (\(\Delta H_1^\circ\)) to that of Reaction 2 (\(\Delta H_2^\circ\)) and provides the correct justification?

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