AP Chemistry
3.2 Properties of Solids
A student compares the structures and conductivities of three carbon allotropes. In a solid, electrical current requires mobile charged particles, whereas thermal energy can be transferred by mobile electrons or by vibrations transmitted through a bonded lattice.
Which of the following statements best accounts for the conductivity data?
| Allotrope | Simplified bonding model | Electrical conductivity | Thermal conductivity |
|---|---|---|---|
| Diamond | Each \(\text{C}\) atom forms \(4\) localized \(\sigma\) bonds in a continuous network. | Very low | High throughout the crystal |
| Graphene | Each \(\text{C}\) atom forms \(3\) localized \(\sigma\) bonds in a planar sheet, and the remaining valence electrons form a delocalized \(\pi\) system within the sheet. | High along the sheet | High along the sheet |
| Graphite | Graphene-like sheets are stacked with weak attractions between sheets; the \(\pi\) electrons are delocalized primarily within each sheet. | High parallel to the sheets and much lower perpendicular to the sheets | High parallel to the sheets and lower perpendicular to the sheets |
Which of the following statements best accounts for the conductivity data?
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