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AP Chemistry
3.6 Deviation from Ideal Gas Law
3.5 Kinetic Molecular Theory
3.1 Intermolecular and Interparticle Forces
AdvancedMCQProportional AnalysisConceptualExperimental25k
A student separately places identical amounts of gaseous ammonia and methane in rigid containers of equal volume. At each temperature, no condensation is observed. The student calculates the ideal-gas pressure using \(P_{\text{ideal}}V=nRT\) and records the following data.

Gas\(\dfrac{P_{\text{measured}}}{P_{\text{ideal}}}\) at \(500\text{ K}\)\(\dfrac{P_{\text{measured}}}{P_{\text{ideal}}}\) at \(300\text{ K}\)
\(\text{NH}_3\text{(g)}\)\(0.98\)\(0.95\)
\(\text{CH}_4\text{(g)}\)\(1.02\)\(1.01\)

Which of the following statements best explains why the pressure ratio for \(\text{NH}_3\text{(g)}\) is lower than that for \(\text{CH}_4\text{(g)}\) and decreases more upon cooling?

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