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AP Chemistry
1.5 Atomic Structure and Electron Configuration
AdvancedMCQConceptual15.2k
The table below shows the predicted electron configurations based on the standard Aufbau principle alongside the experimentally determined ground-state electron configurations for neutral gaseous atoms of three first-row transition metals.

ElementAtomic NumberPredicted ConfigurationObserved Ground-State Configuration
\(\text{V}\)\(23\)\([\text{Ar}]\, 4s^2 3d^3\)\([\text{Ar}]\, 4s^2 3d^3\)
\(\text{Cr}\)\(24\)\([\text{Ar}]\, 4s^2 3d^4\)\([\text{Ar}]\, 4s^1 3d^5\)
\(\text{Cu}\)\(29\)\([\text{Ar}]\, 4s^2 3d^9\)\([\text{Ar}]\, 4s^1 3d^{10}\)

Which of the following statements best explains why the ground-state electron configuration of a neutral \(\text{Cr}\) atom is \([\text{Ar}]\, 4s^1 3d^5\) rather than \([\text{Ar}]\, 4s^2 3d^4\)?

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