AP Chemistry
1.5 Atomic Structure and Electron Configuration
The table below shows the predicted electron configurations based on the standard Aufbau principle alongside the experimentally determined ground-state electron configurations for neutral gaseous atoms of three first-row transition metals.
Which of the following statements best explains why the ground-state electron configuration of a neutral \(\text{Cr}\) atom is \([\text{Ar}]\, 4s^1 3d^5\) rather than \([\text{Ar}]\, 4s^2 3d^4\)?
| Element | Atomic Number | Predicted Configuration | Observed Ground-State Configuration |
|---|---|---|---|
| \(\text{V}\) | \(23\) | \([\text{Ar}]\, 4s^2 3d^3\) | \([\text{Ar}]\, 4s^2 3d^3\) |
| \(\text{Cr}\) | \(24\) | \([\text{Ar}]\, 4s^2 3d^4\) | \([\text{Ar}]\, 4s^1 3d^5\) |
| \(\text{Cu}\) | \(29\) | \([\text{Ar}]\, 4s^2 3d^9\) | \([\text{Ar}]\, 4s^1 3d^{10}\) |
Which of the following statements best explains why the ground-state electron configuration of a neutral \(\text{Cr}\) atom is \([\text{Ar}]\, 4s^1 3d^5\) rather than \([\text{Ar}]\, 4s^2 3d^4\)?
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