AP Chemistry
9.5 Free Energy and Equilibrium
A student measures the equilibrium concentration of hydronium ion in a \(0.10 \text{ M}\) aqueous solution of a weak monoprotic acid, \(\text{HA(aq)}\), at \(298 \text{ K}\).
\[ \text{HA(aq)} + \text{H}_2\text{O(l)} \rightleftharpoons \text{H}_3\text{O}^+\text{(aq)} + \text{A}^-\text{(aq)} \]
At equilibrium, \([\text{H}_3\text{O}^+] = 1.0 \times 10^{-3} \text{ M}\).
Useful information at \(298 \text{ K}\):
Based on these data, what is the value of \(\Delta G^\circ\) for the ionization of \(\text{HA(aq)}\) at \(298 \text{ K}\)?
\[ \text{HA(aq)} + \text{H}_2\text{O(l)} \rightleftharpoons \text{H}_3\text{O}^+\text{(aq)} + \text{A}^-\text{(aq)} \]
At equilibrium, \([\text{H}_3\text{O}^+] = 1.0 \times 10^{-3} \text{ M}\).
Useful information at \(298 \text{ K}\):
- \(RT \approx 2.48 \text{ kJ/mol}\)
- \(\ln(1.0 \times 10^{-6}) \approx -13.8\)
- \(\ln(1.0 \times 10^{-5}) \approx -11.5\)
- \(\ln(1.0 \times 10^{-3}) \approx -6.9\)
Based on these data, what is the value of \(\Delta G^\circ\) for the ionization of \(\text{HA(aq)}\) at \(298 \text{ K}\)?
Similar Questions
Tools for a 5
AP aligned mock tests to help you get a 5.
With grading, adaptive explanations, and more.
Find a Quiz
Find, solve, and grade every AP FRQ ever.
Find an FRQ
Stuck on AP Chemistry? Get unstuck with an AP specialist.1 to 1 tutors who know the exam inside out. Understand weeks of material in a single session.Book a SessionSee all our elite tutors
Learn AP Physics from scratch, quickly. This is the only course you'll need for the year.
A self-paced course with everything you need to get a 5. Trusted by over 15,000 students and 200+ schools. Learn fast, or we'll refund your purchase, backed by our 100% satisfaction guarantee.
Explore the Course