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AP Chemistry
2.3 Structure of Ionic Solids
IntermediateMCQMathematicalConceptual13.2k
A student compares the thermodynamic and structural properties of four crystalline solids at \(298\text{ K}\), as summarized in the table below.

CompoundCationAnionInternuclear distance (\(\text{pm}\))Lattice energy (\(\text{kJ/mol}\))
\(\text{NaF}\)\(\text{Na}^+\)\(\text{F}^-\)\(235\)\(923\)
\(\text{NaCl}\)\(\text{Na}^+\)\(\text{Cl}^-\)\(283\)\(786\)
\(\text{CaO}\)\(\text{Ca}^{2+}\)\(\text{O}^{2-}\)\(240\)\(3414\)
\(\text{MgO}\)\(\text{Mg}^{2+}\)\(\text{O}^{2-}\)\(212\)\(3791\)

Based on the data in the table and Coulomb's law, which of the following best explains why the lattice energy of \(\text{CaO}\) is approximately four times greater than the lattice energy of \(\text{NaF}\)?

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