AP Chemistry
2.3 Structure of Ionic Solids
A student compares the thermodynamic and structural properties of four crystalline solids at \(298\text{ K}\), as summarized in the table below.
Based on the data in the table and Coulomb's law, which of the following best explains why the lattice energy of \(\text{CaO}\) is approximately four times greater than the lattice energy of \(\text{NaF}\)?
| Compound | Cation | Anion | Internuclear distance (\(\text{pm}\)) | Lattice energy (\(\text{kJ/mol}\)) |
|---|---|---|---|---|
| \(\text{NaF}\) | \(\text{Na}^+\) | \(\text{F}^-\) | \(235\) | \(923\) |
| \(\text{NaCl}\) | \(\text{Na}^+\) | \(\text{Cl}^-\) | \(283\) | \(786\) |
| \(\text{CaO}\) | \(\text{Ca}^{2+}\) | \(\text{O}^{2-}\) | \(240\) | \(3414\) |
| \(\text{MgO}\) | \(\text{Mg}^{2+}\) | \(\text{O}^{2-}\) | \(212\) | \(3791\) |
Based on the data in the table and Coulomb's law, which of the following best explains why the lattice energy of \(\text{CaO}\) is approximately four times greater than the lattice energy of \(\text{NaF}\)?
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