AP Chemistry
7.11 Introduction to Solubility Equilibria
7.9 Introduction to Le Châtelier’s Principle
A student investigates the dissolution of a sparingly soluble salt, \(\text{PbI}_2\text{(s)}\), in pure water at three different temperatures. The experimental data collected are shown in the table below.
The dissolution equilibrium is represented by the following equation:
\[ \text{PbI}_2(s) \rightleftharpoons \text{Pb}^{2+}(aq) + 2\,\text{I}^-(aq) \]
Which of the following claims about the standard enthalpy of dissolution, \(\Delta H^\circ_{\text{soln}}\), is best supported by the data?
| Temperature (\(\text{K}\)) | Molar Solubility (\(\text{mol}\cdot\text{L}^{-1}\)) |
|---|---|
| \(283\) | \(1.2 \times 10^{-3}\) |
| \(298\) | \(1.7 \times 10^{-3}\) |
| \(313\) | \(2.5 \times 10^{-3}\) |
The dissolution equilibrium is represented by the following equation:
\[ \text{PbI}_2(s) \rightleftharpoons \text{Pb}^{2+}(aq) + 2\,\text{I}^-(aq) \]
Which of the following claims about the standard enthalpy of dissolution, \(\Delta H^\circ_{\text{soln}}\), is best supported by the data?
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