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AP Chemistry
6.7 Bond Enthalpies
2.2 Intramolecular Force and Potential Energy
Multi-Unit
AdvancedMCQGraphicalConceptual17.3k
A grayscale line graph displays potential energy in \(\text{kJ/mol}\) on the vertical axis versus internuclear distance in \(\text{pm}\) on the horizontal axis. A horizontal dashed zero line is marked at \(0\text{ kJ/mol}\). Three distinct smooth curves (Curve 1, Curve 2, Curve 3) are plotted. All three curves rise steeply toward positive potential energy at internuclear distances below \(60\text{ pm}\), reach a well minimum at a negative potential energy, and approach \(0\text{ kJ/mol}\) asymptotically as internuclear distance exceeds \(300\text{ pm}\). Curve 1 (solid line) has its minimum at \((110\text{ pm}, -945\text{ kJ/mol})\). Curve 2 (dashed line) has its minimum at \((121\text{ pm}, -498\text{ kJ/mol})\). Curve 3 (dotted line) has its minimum at \((142\text{ pm}, -155\text{ kJ/mol})\). A legend in the upper right identifies: solid line = Curve 1, dashed line = Curve 2, dotted line = Curve 3. No other curves, data points, labels, text, or annotations appear.
Potential energy curves for \(\text{N}_2\text{(g)}\), \(\text{O}_2\text{(g)}\), and \(\text{F}_2\text{(g)}\) as a function of internuclear distance.
The potential energy curves for three neutral homonuclear diatomic molecules in the gas phase, \(\text{N}_2\text{(g)}\), \(\text{O}_2\text{(g)}\), and \(\text{F}_2\text{(g)}\), are shown in the graph below as a function of internuclear distance.

Which of the following correctly identifies the curve corresponding to \(\text{O}_2\text{(g)}\) and provides the best justification based on the graph and principles of chemical bonding?

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