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AP Chemistry
8.9 Henderson-Hasselbalch Equation
8.8 Properties of Buffers
8.5 Acid-Base Titrations
8.3 Weak Acid and Base Equilibria
AdvancedMCQGraphicalConceptual17.8k
A titration graph plotting \(\text{pH}\) on the vertical y-axis (scale \(0\) to \(14\), gridlines every \(2\) units) versus Volume of \(0.100\text{ M }\text{NaOH}\) added (\(\text{mL}\)) on the horizontal x-axis (scale \(0\) to \(60\), gridlines every \(10\text{ mL}\)). A legend in the upper left indicates: solid line = Acid 1, dashed line = Acid 2. Curve 1 (solid line) starts at \(\text{pH} = 2.5\) at \(0\text{ mL}\), shows a buffer plateau at \(\text{pH} = 3.8\) at \(12.5\text{ mL}\), a first inflection at \(25.0\text{ mL}\) (\(\text{pH} = 6.0\)), a second buffer plateau at \(\text{pH} = 8.2\) at \(37.5\text{ mL}\), a second inflection at \(50.0\text{ mL}\) (\(\text{pH} = 10.0\)), and levels off at \(\text{pH} = 12.5\). Curve 2 (dashed line) starts at \(\text{pH} = 0.7\) at \(0\text{ mL}\), rises smoothly below \(\text{pH} = 2.0\) until \(45\text{ mL}\), undergoes a single steep inflection at \(50.0\text{ mL}\) through \(\text{pH} = 7.0\), and merges with Curve 1. No other curves, points, labels, or annotations appear.
Titration curves for \(25.0\text{ mL}\) samples of two \(0.100\text{ M}\) diprotic acids titrated with \(0.100\text{ M }\text{NaOH}\).
A student titrates separate \(25.0\text{ mL}\) samples of two different \(0.100\text{ M}\) diprotic acids, Acid 1 (\(\text{H}_2\text{A}\)) and Acid 2 (\(\text{H}_2\text{B}\)), with a standardized \(0.100\text{ M }\text{NaOH(aq)}\) solution at \(298\text{ K}\). The resulting titration curves are shown in the graph below.

Which of the following statements correctly explains the differences in the shapes of the two curves and the number of equivalence points observed?

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