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AP Chemistry
9.8 Galvanic (Voltaic) and Electrolytic Cells
IntermediateMCQConceptualExperimental24.5k
A grayscale schematic diagram of a galvanic cell. On the left, a beaker labeled 1.0 M Zn(NO3)2(aq) contains a solid rectangular strip labeled Zn(s). On the right, a beaker labeled 1.0 M Cu(NO3)2(aq) contains a solid rectangular strip labeled Cu(s). A wire connects the two solid strips through a central circular meter labeled V displaying +1.10 V. An inverted U-tube labeled KNO3(aq) salt bridge dips its ends into both beakers. No other particles, labels, text, or annotations appear.
Galvanic cell operating under standard conditions at \(298\text{ K}\).
A student constructs the galvanic cell represented below at \(298\text{ K}\).

\[\text{Zn(s)} + \text{Cu}^{2+}\text{(aq)} \rightarrow \text{Zn}^{2+}\text{(aq)} + \text{Cu(s)}\quad E^\circ_{\text{cell}} = +1.10\text{ V}\]

The cell consists of a \(\text{Zn(s)}\) electrode in \(1.0\text{ M } \text{Zn(NO}_3)_2\text{(aq)}\) and a \(\text{Cu(s)}\) electrode in \(1.0\text{ M } \text{Cu(NO}_3)_2\text{(aq)}\), connected by an external wire with a voltmeter and a salt bridge containing \(\text{KNO}_3\text{(aq)}\). While current is flowing and the voltmeter displays \(+1.10\text{ V}\), the student removes the salt bridge from both beakers. Which of the following best predicts and explains the immediate change in the voltmeter reading?

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