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AP Chemistry
9.4 Thermodynamic and Kinetic Control
9.3 Gibbs Free Energy and Thermodynamic Favorability
IntermediateMCQMathematicalConceptualExperimental23.4k
A student investigates the oxidation of carbon monoxide in two sealed vessels at \(298\ \text{K}\). The vessels have the same volume and initially contain the same partial pressures of \(\text{CO(g)}\) and \(\text{O}_2\text{(g)}\). The reaction and its standard Gibbs free-energy change are shown below.

\(2\text{CO(g)}+\text{O}_2\text{(g)}\rightarrow 2\text{CO}_2\text{(g)}\qquad \Delta G^\circ_{\mathrm{rxn}}=-514\ \text{kJ/mol}_{\mathrm{rxn}}\)

Surface in vesselPercentage of \(\text{CO(g)}\) converted after \(30\ \text{min}\)
Uncoated ceramicLess than \(1\%\)
Palladium-coated ceramicApproximately \(70\%\)

Which statement best explains both the sign of \(\Delta G^\circ_{\mathrm{rxn}}\) and the difference between the results?

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