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AP Chemistry
9.10 Cell Potential Under Nonstandard Conditions
9.9 Cell Potential and Free Energy
9.8 Galvanic (Voltaic) and Electrolytic Cells
9.5 Free Energy and Equilibrium
IntermediateMCQMathematicalConceptualExperimental25k
A student constructs a concentration cell to model the transfer of copper ions between two recycling streams. Two equal-volume solutions of \(\text{CuSO}_4\text{(aq)}\), initially \(1.0\text{ M}\) and \(0.010\text{ M}\), are connected by a salt bridge. A \(\text{Cu(s)}\) electrode is placed in each solution, and the electrodes are connected through an external circuit. As the cell operates at constant temperature, the student records the following data.

Stage\(\dfrac{[\text{Cu}^{2+}]_{\text{high}}}{[\text{Cu}^{2+}]_{\text{low}}}\)\(E_{\text{cell}}\) (V)
Initial1000.059
Later100.030
Later20.009
Equilibrium10.000

Which statement best explains why the measured cell potential approaches \(0.000\text{ V}\)?

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