AP Chemistry
2.4 Structure of Metals and Alloys
2.3 Structure of Ionic Solids
2.1 Types of Chemical Bonds
A student screens materials for use in a high-temperature electrical feedthrough. The student uses an operational model in which a bond between a metal and a nonmetal has predominantly ionic character when \(\Delta\chi>1.7\). A bond between two nonmetals is polar covalent when \(0.5\leq\Delta\chi\leq1.7\) and nonpolar covalent when \(\Delta\chi<0.5\). A material composed only of metals is evaluated for metallic bonding by using its conductivity and mechanical behavior.
Which assignment of dominant bonding character is most consistent with both the model and the data?
| Sample | Types of constituent elements | Electronegativity values, \(\chi\) | Solid conductivity, \(\sigma\) \((\text{S}\,\text{m}^{-1})\) | Conductivity after melting, \(\sigma\) \((\text{S}\,\text{m}^{-1})\) | Mechanical behavior as a solid |
|---|---|---|---|---|---|
| \(\text{MgO}\) | metal and nonmetal | \(1.3,\ 3.4\) | \(<1\times10^{-10}\) | \(3\times10^{2}\) | Shatters under applied force |
| \(\text{ICl}\) | two nonmetals | \(2.7,\ 3.2\) | \(<1\times10^{-10}\) | \(<1\times10^{-10}\) | Shatters under applied force |
| \(\text{Cu-Ni}\) alloy | two metals | \(1.9,\ 1.9\) | \(2\times10^{6}\) | \(1\times10^{6}\) | Deforms without shattering |
Which assignment of dominant bonding character is most consistent with both the model and the data?
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