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AP Chemistry
2.4 Structure of Metals and Alloys
2.3 Structure of Ionic Solids
2.1 Types of Chemical Bonds
AdvancedMCQDrawing RepresentationsMathematicalConceptual17.7k
A student screens materials for use in a high-temperature electrical feedthrough. The student uses an operational model in which a bond between a metal and a nonmetal has predominantly ionic character when \(\Delta\chi>1.7\). A bond between two nonmetals is polar covalent when \(0.5\leq\Delta\chi\leq1.7\) and nonpolar covalent when \(\Delta\chi<0.5\). A material composed only of metals is evaluated for metallic bonding by using its conductivity and mechanical behavior.

SampleTypes of constituent elementsElectronegativity values, \(\chi\)Solid conductivity, \(\sigma\) \((\text{S}\,\text{m}^{-1})\)Conductivity after melting, \(\sigma\) \((\text{S}\,\text{m}^{-1})\)Mechanical behavior as a solid
\(\text{MgO}\)metal and nonmetal\(1.3,\ 3.4\)\(<1\times10^{-10}\)\(3\times10^{2}\)Shatters under applied force
\(\text{ICl}\)two nonmetals\(2.7,\ 3.2\)\(<1\times10^{-10}\)\(<1\times10^{-10}\)Shatters under applied force
\(\text{Cu-Ni}\) alloytwo metals\(1.9,\ 1.9\)\(2\times10^{6}\)\(1\times10^{6}\)Deforms without shattering

Which assignment of dominant bonding character is most consistent with both the model and the data?

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