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AP Chemistry
3.10 Solubility
3.7 Solutions and Mixtures
3.1 Intermolecular and Interparticle Forces
AdvancedMCQConceptualExperimental16.1k
A student investigates how each of the following solutes partitions between equal-volume layers of water, \(\text{H}_2\text{O}\), and hexane, \(\text{C}_6\text{H}_{14}\), at \(25^\circ\text{C}\).

TrialSolute
AcidDodecanoic acid, \(\text{CH}_3(\text{CH}_2)_{10}\text{COOH}\)
SaltSodium dodecanoate, composed of \(\text{Na}^{+}\) and \(\text{CH}_3(\text{CH}_2)_{10}\text{COO}^{-}\)

The concentrations are low enough that aggregation of the solute particles can be neglected. After each mixture reaches equilibrium, the student defines the distribution ratio as
\[ D=\dfrac{c_{\mathrm{water}}}{c_{\mathrm{hexane}}} \]
where each concentration represents the total dissolved solute in that layer. Compared with \(D\) for dodecanoic acid, which prediction for \(D\) for sodium dodecanoate is best supported?

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