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AP Chemistry
5.9 Pre-Equilibrium Approximation
5.8 Reaction Mechanism and Rate Law
5.7 Introduction to Reaction Mechanisms
5.4 Elementary Reactions
5.2 Introduction to Rate Law
AdvancedMCQMathematicalConceptual16.3k
A chemist studies the vapor-phase formation of a hypothetical coating precursor according to the overall reaction

\[ \text{AX(g)}+\text{B(g)}+\text{X(g)}\rightarrow\text{ABX}_2\text{(g)} \]

Initial-rate measurements at constant temperature give the following rate law.

\[ \text{rate}=k_{\mathrm{obs}}\dfrac{[\text{AX}][\text{B}]}{[\text{X}]} \]

The chemist proposes the mechanism below. Each step is elementary, and step \(1\) rapidly reaches equilibrium before the slow step occurs.

StepProposed elementary process
\(1\)\(\text{AX(g)}\rightleftharpoons\text{A(g)}+\text{X(g)}\), fast equilibrium, \(K_c=\dfrac{k_1}{k_{-1}}\)
\(2\)\(\text{A(g)}+\text{B(g)}\rightarrow\text{AB(g)}\), slow
\(3\)\(\text{AB(g)}+\text{X(g)}\rightarrow\text{ABX(g)}\), fast
\(4\)\(\text{ABX(g)}+\text{X(g)}\rightarrow\text{ABX}_2\text{(g)}\), fast

Which of the following correctly evaluates whether the proposed mechanism is consistent with both the overall reaction and the observed rate law?

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