AP Chemistry
5.9 Pre-Equilibrium Approximation
5.8 Reaction Mechanism and Rate Law
5.7 Introduction to Reaction Mechanisms
5.4 Elementary Reactions
5.2 Introduction to Rate Law
A chemist studies the vapor-phase formation of a hypothetical coating precursor according to the overall reaction
\[ \text{AX(g)}+\text{B(g)}+\text{X(g)}\rightarrow\text{ABX}_2\text{(g)} \]
Initial-rate measurements at constant temperature give the following rate law.
\[ \text{rate}=k_{\mathrm{obs}}\dfrac{[\text{AX}][\text{B}]}{[\text{X}]} \]
The chemist proposes the mechanism below. Each step is elementary, and step \(1\) rapidly reaches equilibrium before the slow step occurs.
Which of the following correctly evaluates whether the proposed mechanism is consistent with both the overall reaction and the observed rate law?
\[ \text{AX(g)}+\text{B(g)}+\text{X(g)}\rightarrow\text{ABX}_2\text{(g)} \]
Initial-rate measurements at constant temperature give the following rate law.
\[ \text{rate}=k_{\mathrm{obs}}\dfrac{[\text{AX}][\text{B}]}{[\text{X}]} \]
The chemist proposes the mechanism below. Each step is elementary, and step \(1\) rapidly reaches equilibrium before the slow step occurs.
| Step | Proposed elementary process |
|---|---|
| \(1\) | \(\text{AX(g)}\rightleftharpoons\text{A(g)}+\text{X(g)}\), fast equilibrium, \(K_c=\dfrac{k_1}{k_{-1}}\) |
| \(2\) | \(\text{A(g)}+\text{B(g)}\rightarrow\text{AB(g)}\), slow |
| \(3\) | \(\text{AB(g)}+\text{X(g)}\rightarrow\text{ABX(g)}\), fast |
| \(4\) | \(\text{ABX(g)}+\text{X(g)}\rightarrow\text{ABX}_2\text{(g)}\), fast |
Which of the following correctly evaluates whether the proposed mechanism is consistent with both the overall reaction and the observed rate law?
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