All questions
AP Chemistry
5.9 Pre-Equilibrium Approximation
5.8 Reaction Mechanism and Rate Law
AdvancedMCQMathematical16.6k
The gas-phase reaction between nitric oxide and chlorine is represented by the balanced equation
\[ 2\,\text{NO}(g) + \text{Cl}_2(g) \rightarrow 2\,\text{NOCl}(g) \]
A proposed mechanism for the reaction consists of two elementary steps:

Step 1 (fast equilibrium): \(\text{NO}(g) + \text{Cl}_2(g) \underset{k_{-1}}{\overset{k_1}{\rightleftharpoons}} \text{NOCl}_2(g)\) \quad (\(k_1 = 2.0 \times 10^4 \text{ M}^{-1}\cdot\text{s}^{-1}\), \(k_{-1} = 5.0 \times 10^2 \text{ s}^{-1}\))

Step 2 (slow): \(\text{NOCl}_2(g) + \text{NO}(g) \xrightarrow{k_2} 2\,\text{NOCl}(g)\) \quad (\(k_2 = 5.0 \times 10^1 \text{ M}^{-1}\cdot\text{s}^{-1}\))

A reaction vessel at the same temperature is initially filled such that \([\text{NO}] = 0.020 \text{ M}\) and \([\text{Cl}_2] = 0.050 \text{ M}\). Based on the proposed mechanism, what is the initial rate of the reaction?

Log In to Continue

Accounts are free! Log in to try this question, see explanations, save progress, and more!

Tools for a 5